(Acetyl­acetonato-κ2 O,O′)dichlorido­bis(methano­lato-κO)niobium(V)

نویسندگان

  • Leandra Herbst
  • Hendrik G. Visser
  • Andreas Roodt
  • Carla Pretorius
چکیده

In the title compound, [Nb(CH(3)O)(2)(C(5)H(7)O(2))Cl(2)], a slightly distorted octa-hedral coordination geometry is observed around the Nb(V) atom with Nb-O distances in the range of 1.8254 (16)-2.0892 (16) Å and Nb-Cl distances of 2.3997 (14) and 2.4023 (12) Å. The O-Nb-O angles vary between 81.36 (7) and 172.65 (7) °, while the trans Cl-Nb-Cl angle is 167.34 (2)°. There are no hydrogen bonds observed.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012